Topic > Methods for the synthesis of nanocrystalline silicate phosphors

The trivalent europium ion (Eu3+) has attracted the attention of researchers for a long time for many reasons. Due caution is given due to the strong luminescence in the red spectral region. Its even number of electrons in the outermost 4f shell has drawn researchers' attention towards it due to the theoretical importance of the structure. Rare earth-doped nanophosphors have been the focus of research because in display devices or LED applications they overcome the disadvantage of self-absorption and tunable luminescence. Yttrium orthosilicate (YSO) has proven to be an excellent host material for rare earth elements due to special properties such as water resistance, chemical resistance and visible light transparency. Furthermore, they exhibit superior properties due to thermal stability, wide energy band range, low cost, non-toxicity, chemical resistance, high temperature resistance, low thermal expansion and high conductivity, multi-color phosphorescence, high resistance to acids, alkalis and oxygen. Among silicate phosphors, rare earth ion-doped YSOs are widely studied in display applications. YSO has proven to be an excellent cathodoluminescent material and, doped with Eu3+, is a promising candidate for time-domain coherent optical memory and red phosphor for lamps and display applications. Say no to plagiarism. Get a tailor-made essay on "Why Violent Video Games Shouldn't Be Banned"? Get Original Essay The luminescence properties of Eu3+ doped compounds have been extensively studied in various compound forms such as solutions, polymer compounds, liquid crystals, glasses, etc. These compounds have been prepared via various conventional methods. Silicate nanophosphors are synthesized via a variety of routes such as solid-state, sol-gel, hydrothermal, co-precipitation, and spray pyrolysis reactions. It has also been established that the synthesis method and conditions influence the luminescence properties. In the present study, Eu3+ doped YSO nanophosphorus (1–9 mol %) was synthesized sonochemically. The prepared sample was calcined at 11,000°C and 13,000°C. Due to the quantum confinement effects of incorporating trivalent rare earth cations into a host lattice, the properties of the nanophosphorus are substantially improved. The Eu3+ doped YSO phosphor emits in the red region with appreciable color purity. The nanophosphor is excited by near-ultraviolet light. An in-depth study on YSO:Eu3+ synthesized via sonochemical method has not been reported so far. This study is an effort to probe the crystal structure of the prepared nanophosphor by studying its photoluminescence. A reaction is a way of interaction of energy with matter. Controlling a reaction is nothing more than controlling matter and energy or both. The preparation of nanoparticles requires effective control over the chemical reaction leading to their synthesis, which is a complex task. The method or procedure of synthesis of nanomaterials influences their properties. In order to prepare nanomaterials as needed, various reaction parameters such as time, energy input and pressure are generally manipulated. But the main constraint is selecting the appropriate energy source. Sonochemical methods involving ultrasonic irradiation have recently been given importance since they provide rare reaction conditions that are superior to other conventional methods. Acoustic cavitation is the key event leading to unusual reaction conditions in the sonochemical synthesis method. When reaction liquids are exposed to ultrasound, acoustic waves.